San José State University

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Quantitative Analysis of Relationships
Concerning Binding Energy and Number
of Neutrons in Nuclides

The binding energies are known for about three thousand nuclides. When these values are used to construct profiles of binding energy versus the number of neutrons for various elements these profiles display some interesting characteristics. First the profiles are parabolic with binding energy increasing at a decreasing rate as neutrons are added. More interesting is the incremental increases which display a downward, almost linear, trend with fluctuations associated with the formation of neutron pairs. At particular numbers the incremental values decrease and the magnitude of the fluctuations due to pair formation changes. For example, here is the profile of incremental increases for bromine.

The break in the relationship occurs at the point where the number of neutrons is 50. Fifty is one of the so-called magic numbers of nuclear structure. For more on magic numbers in nuclear structure see Magic Numbers 0, Magic Numbers I, and Magic Numbers II.

The relationship between incremental binding energy ΔB and the number of additional neutrons n can be approximated by a function of the form

ΔB = c0 + c1n + c2u

where if Z is the number of protons and N the number of neutrons for a nuclide then n=N-Z. The variable u reflecting neutron pair formation is equal to zero if N is odd and unity if N is evern. The regression coefficient c0 is called the intercept and c1 the slope.

There are indications that these regression parameters may reveal information about the structure of nuclei. For example, the magnitude of the slope may be inversely proportional to the radius of the shell that is being filled. For many elements there are two regression lines. For example, for the case of bromine shown above there is a regression for the data below the break and another one for the data above the break.

Given below are the regression parameter estimates for an arbitrary selection of elements. It is notable that for elements close in atomic number Z the parameters are close in values.

Regression Equation Parameters for the
Relationships Between Incremental Increases in
Binding Energy and the Number of Neutrons
in Excess of the Protons in Nuclides
ElementNumber
of Protons
Intercept    Slope     Pair
Formation
Increment
Coefficient of
Determination
Degrees of
Freedom
The 82-to-126 Neutron Shell
Uranium927.23582-0.116051.511210.96321
Polonium849.09554-0.134611.928210.95517
Bismuth8312.26606-0.131011.470340.98121
Lead8211.66121-0.129152.133600.96324
Mercury8011.44383-0.140512.170440.97928
Gold7911.92086-0.140321.526790.98533
Cesium557.96838-0.121691.289260.98711
The 50-to-82 Neutron Shell
Cesium5511.80531-0.210101.980550.98722
Xenon5410.88332-0.205682.600390.98523
Iodine5310.79384-0.195132.226960.98724
Tellurium5210.45359-0.197052.690910.98425
Antimony5110.64351-0.193252.246610.98624
Tin5010.54740-0.192302.627400.98329
Indium4910.58613-0.19952.212730.98323
Cadmium4810.28301-0.201662.664030.98429
Silver4710.46401-0.205702.029700.98427
Palladium4610.11712-0.213522.583060.98724
Rhodium4510.20289-0.214472.082780.99023
Ruthenium449.92022-0.220332.457780.99021
Technetium4310.36545-0.243222.210820.94820
Molybdenum429.63716-0.220852.243180.98718
Niobium4110.46348-0.259281.886340.90917
Zirconium409.59217-0.226051.677000.95615
Yttrium3910.61462-0.273041.345850.81915
Rubidium3711.45052-0.274811.977220.9629
Krypton369.58940-0.276561.764890.9648
Bromine3510.99744-0.298322.365960.9945
The 28-to-50 Neutron Shell
Niobium4111.73750-0.237502.237500.9715
Yttrium3911.32410-0.223752.285450.9767
Strontium388.83274-0.222472.159950.9798
Rubidium3710.96541-0.224812.011490.9629
Bromine3512.81863-0.447031.798000.90112
Selenium3410.43328-0.323363.49824
Arsenic3310.66552-0.313602.437480.99212
Titanium229.11722-0.424751.979480.973
20 to 28 Neutron Shell
Titanium2210.21436-0.454783.523210.982
Calcium208.65859-0.227983.21944
Argon187.65135-0.271593.181860.984
The 14-to-20 Neutron Shell
Sulfur169.40556 -0.79593 3.63517
Silicon149.16356 -0.883013.48451
Magnesium127.29294-0.604623.300730.9618
The 8-to-14 Neutron Shell
Neon107.510346 -0.764744.39858
Oxygen84.54168-0.191053.724183
Carbon61.96729-0.255503.491860.9954

The data in the table demonstrates the systematic variation in the regression parameters with the atomic number of the elements, the number of protons. The graph below shows the relationship between the magnitude of the slope and the proton number for the elements which reflect the filling of the 50-to-82 neutron shell. The data is shown only for the elements with an even number of protons to avoid the effect of the nonformation of alpha particles within the nucleus.

The slopes may inversely proportional to the radius of the shell. If so the above relationship indicates that the radius of the shell is larger for nuclides with more protons. This could reasonably be expected as a result of the electrostatic repulsion of the protons.

For shells of electrons the ratio of the regression intercept to the magnitude of the regression slope is related to the effective charge experienced the electrons in the shell. For the nuclear shells that ratio is correlated with the number of protons in the nucleus, as seen below.

(To be continued.)


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