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Quantitative Analysis of Relationships Concerning
Binding Energy and Number of Neutrons in Nuclides
for the Various Nuclear Shells

The binding energies are known for about three thousand nuclides. When these values are used to construct profiles of binding energy versus the number of neutrons for various elements these profiles display some interesting characteristics. First the profiles are parabolic with binding energy increasing at a decreasing rate as neutrons are added. More interesting is the incremental increases which display a downward, almost linear, trend with fluctuations associated with the formation of neutron pairs. At particular numbers the incremental values decrease sharply and the magnitude of the fluctuations due to pair formation changes. For example, here is the profile of incremental increases for bromine.

The break in the relationship occurs at the point where the number of neutrons is 50. Fifty is one of the so-called magic numbers of nuclear structure. For more on magic numbers in nuclear structure see Magic Numbers 0, Magic Numbers I, and Magic Numbers II.

The relationship between incremental binding energy ΔB and the number of additional neutrons n can be approximated by a function of the form

ΔB = c0 + c1n + c2u

where if Z is the number of protons and N the number of neutrons for a nuclide then n=N-Z. The variable u reflecting neutron pair formation is equal to zero if N is odd and unity if N is evern. The regression coefficient c0 is called the intercept and c1 the slope.

There are indications that these regression parameters may reveal information about the structure of nuclei. For example, the magnitude of the slope may be inversely proportional to the radius of the shell that is being filled. For many elements there are two regression lines. For example, for the case of bromine shown above there is a regression for the data below the break and another one for the data above the break.

Given below are the regression parameter estimates c1 for some of the elements which have data for the various nuclear shells. It is notable that for elements close in atomic number Z the parameters are close in values.


The 50 to 82 Neutron Shell

Regression Equation Slope Parameters for the
Relationships Between Incremental Increases in
Binding Energy and the Number of Neutrons
in Excess of the Protons in Nuclides
ElementNumber
of Protons
    Slope     Pair
Formation
Increment
Coefficient of
Determination
Degrees of
Freedom
The 50-to-82 Neutron Shell
Neodymium60-0.197142.546430.99013
Cerium58-0.214822.535920.98818
Lanthanum57-0.212111.963020.98219
Barium56-0.215942.559610.98821
Cesium55-0.210101.980550.98722
Xenon54-0.205682.600390.98523
Iodine53-0.195132.226960.98724
Tellurium52-0.197052.690910.98425
Antimony51-0.193252.246610.98624
Tin50-0.192302.627400.98329
Indium49-0.19952.212730.98323
Cadmium48-0.201662.664030.98429
Silver47-0.205702.029700.98427
Palladium46-0.213522.583060.98724
Rhodium45-0.214472.082780.99023
Ruthenium44-0.220332.457780.99021
Technetium43-0.243222.210820.94820
Molybdenum42-0.220852.243180.98718
Niobium41-0.259281.886340.90917
Zirconium40-0.226051.677000.95615
Yttrium39-0.273041.345850.81915
Strontium38-0.222472.159950.95313
Rubidium37-0.274811.977220.9629
Krypton36-0.276561.764890.9648
Bromine35-0.322671.424920.9645
Selenium34-0.300681.758420.9755
Arsenic33-0.230001.370000.9991
Germanium32-0.315002.185000.9931

The data in the table demonstrates the systematic variation in the regression parameters with the atomic number of the elements, the number of protons. The graph below shows the relationship between the magnitude of the slope and the proton number for the elements which reflect the filling of the 50-to-82 neutron shell.

For the elements below molybdenum in atomic number the relationship to atomic number (number of protons) is irregular, but above molybdenum it is quite regular.

The parameter of interest is the amount by which the incremental binding energy is enhanced (increased) by neutron pair formation. The graph below shows irregularities below molybdenum but reasonable regularity above molybdenum, however with an odd-even alternation.


The 28 to 50 Neutron Shell

Regression Equation Slope Parameters for the
Relationships Between Incremental Increases in
Binding Energy and the Number of Neutrons
in Excess of the Protons in Nuclides
ElementNumber
of Protons
    Slope     Pair
Formation
Increment
Coefficient of
Determination
Degrees of
Freedom
The 28-to-50 Neutron Shell
Silver47-0.300002.100001.0000
Palladium46-0.267502.73250.9971
Rhodium45-0.148001.753330.9902
Ruthenium44-0.206372.569380.9863
Technetium43-0.174821.703750.9284
Molybdenum42-0.176702.518200.9745
Niobium41-0.237502.237500.9715
Zirconium40-0.218752.814940.9767
Yttrium39-0.223752.285450.9767
Strontium38-0.269032.955100.9798
Rubidium37-0.224812.011490.9628
Krypton36-0.303853.165420.99111
Bromine35-0.298322.365960.99412
Selenium34-0.323363.498240.98813
Arsenic33-0.313602.437480.99214
Germanium32-0.331233.329320.98615
Gallium31-0.327082.306230.97916
Zinc30-0.339133.079150.97917
Copper29-0.346922.472080.98117
Nickel28-0.350292.815490.98019
Cobalt27-0.375562.297490.96614
Iron26-0.406612.5814890.96912
Manganese25-0.401491.835500.96211
Chromium24-0.417162.908110.96410
Vanadium23-0.412271.9270.9649
Titanium22-0.424751.979480.9738
Scandium21-0.437280.858080.9347
Calcium20-0.449081.031050.9706
Potassium19-0.498702.078200.9765
Argon18-0.540002.583330.9174
Chlorine17-0.637502.004170.9153
Sulfur16-0.520002.666670.9822

The data in the table demonstrates the systematic variation in the regression parameters with the atomic number of the elements, the number of protons. The graph below shows the relationship between the magnitude of the slope (the slope is negative) and the proton number for the elements which reflect the filling of the 28-to-50 neutron shell.

Except for the few data points at the ends of the range the relationship appears to be linear. The regression equation for the range from Z=20 (calcium) to Z=45 (rhodium) is

|Slope| = 0.68557 − 0.01146Z
R² = 0.962

However close examination of the graph reveal that there are breaks after Z=25 (iron) and Z=36 (krypton). At Z=36 there is not only a reduction in the level of the slope magnitude but the amplitude of the fluctuations in the slope increases.

The other parameter of interest is the amount by which the incremental binding energy is enhanced (increased) by neutron pair formation. The graph below shows irregularities below titanium but reasonable regularity above titanium, however with an odd-even alternation.


The 20 to 28 Neutron Shell

Regression Equation Slope Parameters for the
Relationships Between Incremental Increases in
Binding Energy and the Number of Neutrons
in Excess of the Protons in Nuclides
ElementNumber
of Protons
    Slope     Pair
Formation
Increment
Coefficient of
Determination
Degrees of
Freedom
Manganese25-0.816502.334801.00-0
Chromium24-0.570273.168120.9961
Vanadium23-0.510951.931120.9762
Titanium22-0.454783.53210.9823
Scandium21-0.344122.161920.9954
Calcium20-0.227983.219440.9945
Potassium19-0.225242.090170.9735
Argon18-0.253723.223460.9835
Chlorine17-0.294612.259920.9384
Sulfur16-0.230653.522390.9855
Phosphorus15-0.193612.361760.8445
Silicon14-0.168833.331080.9845
Aluminum13-0.298752.502080.9513
Magnesium12-0.568003.446670.9762
Sodium11-0.69000-0.990001.0001

The data in the table demonstrates the systematic variation in the regression parameters with the atomic number of the elements, the number of protons. The graph below shows the relationship between the magnitude of the slope (the slope is negative) and the proton number for the elements which reflect the filling of the 20-to-28 neutron shell.

Except for the three data points at the lower end of the range and the last data point at the upper end of the range the relationship could be considered to be linear.

The other parameter of interest is the amount by which the incremental binding energy is enhanced (increased) by neutron pair formation. The graph below shows an anomaly for Z=11 (sodium) but reasonable regularity for the other data points, however with an odd-even alternation. The lower points, except for sodium, fall nearly along a straight line.


The 14 to 20 Neutron Shell

Regression Equation Slope Parameters for the
Relationships Between Incremental Increases in
Binding Energy and the Number of Neutrons
in Excess of the Protons in Nuclides
ElementNumber
of Protons
    Slope     Pair
Formation
Increment
Coefficient of
Determination
Degrees of
Freedom
Chlorine17-1.166652.897941.0000
Sulfur16-0.795933.635171.0001
Phosphorus15-0.963203.131300.9961
Silicon14-0.938763.391680.9942
Aluminum13-0.933292.427480.9923
Magnesium12-0.860863.486750.9523
Sodium11-0.783182.094040.9373
Neon10-0.569252.721250.8593
Fluorine9-0.913751.517080.8823
Oxygen8-1.420002.410001.0000
Nitrogen7-1.210002.380001.0000

The data in the table demonstrates the systematic variation in the regression parameters with the atomic number of the elements, the number of protons. The graph below shows the relationship between the magnitude of the slope (the slope is negative) and the proton number for the elements which reflect the filling of the 14-to-20 neutron shell.

Except for the four data points at the lower end of the range and the last two data points at the upper end of the range the relationship could be considered to be linear.

The other parameter of interest is the amount by which the incremental binding energy is enhanced (increased) by neutron pair formation. The graph below shows a reasonable regularity for the data points, however with an odd-even alternation. The lower points, except for Z=7 (nitrogen) and Z=17 (chlorine), fall nearly along a straight line.


The 10 to 14 Neutron Shell

Regression Equation Slope Parameters for the
Relationships Between Incremental Increases in
Binding Energy and the Number of Neutrons
in Excess of the Protons in Nuclides
ElementNumber
of Protons
    Slope     Pair
Formation
Increment
Coefficient of
Determination
Degrees of
Freedom
Magnesium12-0.860863.486750.9523
Sodium11-1.703793.755481.0000
Neon10-0.764744.398581.0001
Fluorine9-0.716382.774340.9652
Oxygen8-0.226103.575300.9921
Nitrogen7-0.345252.820751.0001

The data in the table demonstrates the systematic variation in the regression parameters with the atomic number of the elements, the number of protons. The graph below shows the relationship between the magnitude of the slope (the slope is negative) and the proton number for the elements which reflect the filling of the 20-to-28 neutron shell.

In this case the data consists mostly of the anomalous end points and little regularity can be perceived.

The other parameter of interest is the amount by which the incremental binding energy is enhanced (increased) by neutron pair formation. The graph below shows reasonable regularity for the other data points, however with an odd-even alternation.


The 82 to 126 Neutron Shell

The tabulation of the results for the 82-to-126 neutron shell is not complete but some values are given in the table below to show that the results generally fit into the pattern observed for the other shells. There is also a shell for more than 126 neutrons, but no results are available yet for it.

Regression Equation Parameters for the
Relationships Between Incremental Increases in
Binding Energy and the Number of Neutrons
in Excess of the Protons in Nuclides
ElementNumber
of Protons
    Slope     Pair
Formation
Increment
Coefficient of
Determination
Degrees of
Freedom
The 82-to-126 Neutron Shell
Uranium92-0.116051.511210.96321
Polonium84-0.134611.928210.95517
Bismuth83-0.131011.470340.98121
Lead82-0.129152.133600.96324
Mercury80-0.140512.170440.97928
Gold79-0.140321.526790.98533
Lanthanum57-0.131401.548650.96413
Barium56-0.128342.559610.98821
Cesium55-0.121691.289260.91812

(To be continued.)


Conclusions

The magnitudes of the regression slopes are larger for the lower shells, indicating a possible relationship between the magnitude of the slope and the radius of the shell. The shell radii for each shell type appear to to depend upon the number of protons in the nucleus, its atomic number.



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